The reaction of n-alkylamines CnH2n+1NH2(n= 1–10) with a partially phosphated zirconium carboxyethyl-phosphonate shows that only heptylamine (n= 7) is preferentially intercalated to form a bilayer, demonstrating a new class of host–guest process based on molecular assembly recognition.
T. Kijima, S. Watanabe, K. Ohe and M. Machida, J. Chem. Soc., Chem. Commun., 1995, 75 DOI: 10.1039/C39950000075
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