Methylamines were synthesized from carbon dioxide, hydrogen and ammonia over Cu–Al2O3 catalysts, affording a distribution of monomethylamine:dimethylamine:trimethylamine of 1:0.23:0.07.
S. V. Gredig, R. A. Koeppel and A. Baiker, J. Chem. Soc., Chem. Commun., 1995, 73 DOI: 10.1039/C39950000073
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