Employing fast time-resolved infrared (TRIR) spectroscopy, the pattern of the ν(CO) IR bands in the lowest excited state of [(OC)5W(4,4′-bipy)W(CO)5](4,4′-bipy = 4,4′-bipyridyl) shows that the electron distribution in this state is localised on the IR time-scale.
M. W. George, J. J. Turner and J. R. Westwell, J. Chem. Soc., Dalton Trans., 1994, 2217 DOI: 10.1039/DT9940002217
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