Issue 14, 1994

Synthetic and structural characterisation of metal complexes of ferrocenylacetylene: novel donor–acceptor heterobimetallic materials

Abstract

Two novel metal (ruthenium or osmium) complexes of ferrocenylacetylene have been synthesised and the crystal structure of [Fe(C5H5){C5H4C[triple bond, length half m-dash]C[Os(dppm)2Cl]}][dppm = 1,2-bis(diphenylphosphino)-methane] has been determined; their solution redox chemistry indicated metal–metal interaction via the conjugated ligand group.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 2215-2216

Synthetic and structural characterisation of metal complexes of ferrocenylacetylene: novel donor–acceptor heterobimetallic materials

M. C. B. Colbert, S. L. Ingham, J. Lewis, N. J. Long and P. R. Raithby, J. Chem. Soc., Dalton Trans., 1994, 2215 DOI: 10.1039/DT9940002215

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