Ferro- and ferri-magnetism in oximato-bridged MIIICuII chains (M = Mn and Fe). A molecular based ferromagnet with Tc= 9 K: [MnIIICuII-bis(1,2-cyclohexanedioneoximato)(acetato)(H2O)2]

Francesc Lloret; Rafael Ruiz; Beatriz Cervera; Isabel Castro; Miguel Julve; Juan Faus; José Antonio Real; Fernando Sapiña; Yves Journaux; Jean Christophe Colin; Michel Verdaguer

doi:10.1039/C39940002615

Ferro- and ferri-magnetism in oximato-bridged M^IIICu^II chains (M = Mn and Fe). A molecular based ferromagnet with T_c= 9 K: [Mn^IIICu^II-bis(1,2-cyclohexanedioneoximato)(acetato)(H₂O)₂]

Francesc Lloret, Rafael Ruiz, Beatriz Cervera, Isabel Castro, Miguel Julve, Juan Faus, José Antonio Real, Fernando Sapiña, Yves Journaux, Jean Christophe Colin and Michel Verdaguer

Abstract

The study of the magnetic properties of the compounds [M^IIICu^II(L)₂(MeCO₂)(H₂O)₂], M = Mn and L = dimethylglyoximato (dmg)1 or 1,2-cyclohexanedioneoximato (chd)2 and M = Fe and L = dmg 3, shows that 1 is a metamagnetic compound, 2 is a bulk ferromagnet with T_c= 9 K and 3 orders antiferromagnetically at 7.5 K.

Journal of the Chemical Society, Chemical Communications

Ferro- and ferri-magnetism in oximato-bridged M^IIICu^II chains (M = Mn and Fe). A molecular based ferromagnet with T_c= 9 K: [Mn^IIICu^II-bis(1,2-cyclohexanedioneoximato)(acetato)(H₂O)₂]

Abstract

Article information

Download Citation

Permissions

Ferro- and ferri-magnetism in oximato-bridged M^IIICu^II chains (M = Mn and Fe). A molecular based ferromagnet with T_c= 9 K: [Mn^IIICu^II-bis(1,2-cyclohexanedioneoximato)(acetato)(H₂O)₂]

Search articles by author

Spotlight

Advertisements