Cationic rhodium(I) complexes containing the new chiral bidentate P,N ligand 2-[1-(1S,2S,5R)-(–)menthoxydiphenylphosphino]pyridine are prepared and used successfully in the enantioselective hydroformylation of olefinic substrates, styrene, 2-vinylnaphthalene, methylacrylate and vinylacetate.
C. G. Arena, F. Nicolò, D. Drommi, G. Bruno and F. Faraone, J. Chem. Soc., Chem. Commun., 1994, 2251 DOI: 10.1039/C39940002251
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