Cationic rhodium complex-catalysed highly selective hydrosilylation of propynylic alcohols: a convenient synthesis of (E)-γ-silyl allylic alcohols
Abstract
Cationic rhodium compex-catalysed hydrosilylation of alk-1-ynols including propynylic alcohols with triethylsilane is highly selective to give (E)-1-triethylsilyl alk-1-enols as products in excellent yields.