Cationic rhodium compex-catalysed hydrosilylation of alk-1-ynols including propynylic alcohols with triethylsilane is highly selective to give (E)-1-triethylsilyl alk-1-enols as products in excellent yields.
R. Takeuchi, S. Nitta and D. Watanabe, J. Chem. Soc., Chem. Commun., 1994, 1777 DOI: 10.1039/C39940001777
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