Issue 15, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel bonding modes in metallo–dithiadiazolyl complexes: preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh3)2]·MeCN and [Pt3(µ-SNCPhNS-S,S)2(PPh3)4]·2PhMe

Arthur J. Banister,   Ian B. Gorrell,   Simon E. Lawrence,   Christian W. Lehmann,   Iain May,   Gillian Tate,   Alexander J. Blake  and  Jeremy M. Rawson  

Abstract

Reaction of [Pt(PPh3)3] with (Ph[graphic omitted])2 in MeCN leads to [Pt(SNCPhNS-S-S,S)(PPh3)2]·MeCN, which decomposes in toluene to give a novel trimetallic species, [Pt3(µ-SNCPhNS-S,S)2(PPh3)4]; the structures of both compounds are reported.

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Article information

DOI
https://doi.org/10.1039/C39940001779
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1779-1780

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Novel bonding modes in metallo–dithiadiazolyl complexes: preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh3)2]·MeCN and [Pt3(µ-SNCPhNS-S,S)2(PPh3)4]·2PhMe

A. J. Banister, I. B. Gorrell, S. E. Lawrence, C. W. Lehmann, I. May, G. Tate, A. J. Blake and J. M. Rawson, J. Chem. Soc., Chem. Commun., 1994, 1779 DOI: 10.1039/C39940001779

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