Polymerisation of phenylacetylene occurs in the presence of triethylsilane and Rh+(cod)BPh4– to give stereoregular cis-poly(phenylacetylene) with M![[> with combining macron]](https://www.rsc.org/images/entities/char_003e_0304.gif)
w of up to 35 000 (Mw/Mn= 1.7–5.0).
Y. Goldberg and H. Alper, J. Chem. Soc., Chem. Commun., 1994, 1209 DOI: 10.1039/C39940001209
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