Treatment of [IrCl(CO)2(p-toludine)] with azine phosphines of type Z,E-PPh2CH2C(But)![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
N–NC(Q)R, Q = H or Me, R = an organic group, activates aryl, heterocyclic, alkenyl or aliphatic C–H bonds to give cyclometallated iridium(III) hydrides.
S. D. Perera and B. L. Shaw, J. Chem. Soc., Chem. Commun., 1994, 1203 DOI: 10.1039/C39940001203
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