SCHEDULED MAINTENANCE
Treatment of [RuCl2(PPh3)3] with azine phosphines gives complexes showing strong agostic interactions between ruthenium and C–H bonds of tert-butyl, methyl, aryl or alkenyl groups in dynamic systems; for example, all nine hydrogens of a tert-butyl group are agostically interacting with ruthenium on the NMR timescale at 20 °C.
S. D. Perera and B. L. Shaw, J. Chem. Soc., Chem. Commun., 1994, 1201 DOI: 10.1039/C39940001201
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