SCHEDULED MAINTENANCE
The chiral synthesis of the Sceletium alkaloid, (–)-mesembranol 1 is described; the cyclohexane ring in 1 is prepared in an optically active form from D-glucose using Ferrier's carbocyclisation reaction and the perhydroindole skeleton is effectively constructed by an intramolecular aminomercuration reaction.
N. Chida, K. Sugihara and S. Ogawa, J. Chem. Soc., Chem. Commun., 1994, 901 DOI: 10.1039/C39940000901
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