Issue 11, 1993

Do metal perchlorates act as a conventional Lewis acid in the allylstannation of aldehydes?

Abstract

Lithium, magnesium and calcium perchlorates are found to promote the addition of allylic tin compounds to aldehydes via a six-membered cyclic transition state, although not acting as a conventional Lewis acid like BF3.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1993, 1203-1204

Do metal perchlorates act as a conventional Lewis acid in the allylstannation of aldehydes?

Y. Nishigaichi, N. Nakano and A. Takuwa, J. Chem. Soc., Perkin Trans. 1, 1993, 1203 DOI: 10.1039/P19930001203

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