Issue 11, 1993

Mechanistic pathways for radical ring expansion/aromatisation of steroid C/D models

Abstract

The pathway for ring expansion and aromatisation of the radical 9 to the isomeric tetralins 7 and 10(Scheme 2) has been investigated by deuterium labelling, and a new mechanism (Scheme 5) is put forward.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1993, 1205-1206

Mechanistic pathways for radical ring expansion/aromatisation of steroid C/D models

S. P. Green and D. A. Whiting, J. Chem. Soc., Perkin Trans. 1, 1993, 1205 DOI: 10.1039/P19930001205

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