The title complex {where 5-NO2-salimH2= 4-[2-(5-NO2-salicylideneimine)ethyl]imidazole} has been structurally characterized and is the first µ-phenolato, µ-carboxylato-O, µ-carboxylato-O,O′ type model for the ‘carboxylate shift’ in polymanganese and polyiron enzymes.
M. J. Baldwin, J. W. Kampf and V. L. Pecoraro, J. Chem. Soc., Chem. Commun., 1993, 1741 DOI: 10.1039/C39930001741
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