Issue 23, 1993

Controlled oxidation of enolates to α-carbonyl radicals and α-carbonyl cations

Abstract

Depending on the oxidation strength of the one-electron oxidants either persistent α-carbonyl radicals or α-carbonyl cation derived benzofurans are formed from enolates A1A6, a result which can readily be rationalized by the measured oxidation potentials of enolates A1A6and α-carbonyl radicals R1R6.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1739-1741

Controlled oxidation of enolates to α-carbonyl radicals and α-carbonyl cations

M. Röck and M. Schmittel, J. Chem. Soc., Chem. Commun., 1993, 1739 DOI: 10.1039/C39930001739

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