Issue 18, 1993

π-Face differentiation in Michael reaction to the enone group adjacent to the (η-C5H5)Mo(CO)2(π-allyl) fragment: a new approach to the stereoselective synthesis of 2,3,4,5-tetrasubstituted-tetrahydrofuran compounds

Abstract

The stereochemical outcome of the 1,4-addition of organocopper reagents to (η-C5H5)Mo(CO)23-1-(E)-C3H4COCH[double bond, length half m-dash]CHR] compounds has been elucidated; utilization of this reaction for synthesis of 2,3,4,5-tetrasubstituted tetrahydrofuran is demonstrated.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1391-1393

π-Face differentiation in Michael reaction to the enone group adjacent to the (η-C5H5)Mo(CO)2(π-allyl) fragment: a new approach to the stereoselective synthesis of 2,3,4,5-tetrasubstituted-tetrahydrofuran compounds

S. Lin, W. Cheng, Y. Liao, S. Wang, G. Lee, S. Peng and R. Liu, J. Chem. Soc., Chem. Commun., 1993, 1391 DOI: 10.1039/C39930001391

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