The triene 3 and 6 have been syntesised in specifically labeled from and their incorporation into the macrodiolide, colletodio 1 demonstrated in cultures of Cytospora sp. ATCC 20502; results of a biomimetic reaction indicate that both colletoketol 2 and grahamimycin A17 may be biosynthesized in a single oxidation step from collectodiol.
J. A. O'Neill, T. J. Simpson and C. L. Willis, J. Chem. Soc., Chem. Commun., 1993, 738 DOI: 10.1039/C39930000738
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