Issue 9, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Carbene complexes from coordinated bis(diphenylphosphino)methane. Synthesis and X-ray structure determination of the remarkable heterotrimetallic derivative [{Fe(CNPh)4((PPh2)2C)}2Hg]I2

Javier Ruiz,   René Arauz,   Victor Riera,   Marilin Vivanco,   Santiago García-Granda  and  Enrique Pérez-Carreño  

Abstract

The bis(diphenylphosphino)methanide complexes fac-[Mn(CNBut)(CO)3{(PPh2)2CH}]1a and [Fe(CNPh)4{(PPh2)2CH}]ClO41b react with HgI2 and KOH to give the heterotrimetallic bis(carbene)derivatives fac-[{Mn(CNBut)(CO}3((PPh2)2C)}2 Hg]4a and [{Fe(CNPh)4[(PPh2)2C]}2 Hg]I24b, respectively; the structure of 4b has been determined by X-ray analysis.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39930000740
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 740-742

Permissions

Request permissions

Carbene complexes from coordinated bis(diphenylphosphino)methane. Synthesis and X-ray structure determination of the remarkable heterotrimetallic derivative [{Fe(CNPh)4((PPh2)2C)}2Hg]I2

J. Ruiz, R. Arauz, V. Riera, M. Vivanco, S. García-Granda and E. Pérez-Carreño, J. Chem. Soc., Chem. Commun., 1993, 740 DOI: 10.1039/C39930000740

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements