Issue 20, 1992

Structure of 1-isothiocyanato-2,8,9-trioxa-5-aza-1-germabicyclo[3.3.3]undecane: the first metallatrane with a direct metal–NCS bond

Abstract

A germatrane with a Ge–NCS bond has been isolated and characterised by X-ray crystallography and molecular spectroscopy; [graphic omitted] exhibits the shortest known Ge–N bond distance amongst germatranes and the first 13C–14N coupling [J(13C–14N)= 21.0 Hz] in a five-co-ordinate germanium compound.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 3055-3056

Structure of 1-isothiocyanato-2,8,9-trioxa-5-aza-1-germabicyclo[3.3.3]undecane: the first metallatrane with a direct metal–NCS bond

S. P. Narula, S. Soni, R. Shankar and R. K. Chadha, J. Chem. Soc., Dalton Trans., 1992, 3055 DOI: 10.1039/DT9920003055

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