The reaction between [Ru5(µ3-CCH2)(µ3-SMe)2(µ-PPh2)2(CO)10] and [Fe2(CO)9] afforded the electron-rich mixed-metal cluster [FeRu5(µ4-CCH2)(µ3-SMe)(µ-SMe)(µ-PPh2)2(CO)13], with a symmetrical µ4-vinylidene ligand; the metal core consists of an Ru5 bow-tie, the central and two wing-tip atoms of which are attached to the Fe atom.
C. J. Adams, M. I. Bruce, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1992, 3057 DOI: 10.1039/DT9920003057
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