Issue 13, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Interplay of phosphido and phosphine ligands in dinuclear ruthenium complexes: implication in the catalytic hydroformylation of ethylene

Alain Béguin,   Hans-Christian Böttcher,   Georg Süss-Fink  and  Bernhard Walther  

Abstract

The conversion of the diphenylphosphine complex [Ru2(CO)4(µ-O2CEt)2(PPh2H)2]1 into the diphenylphosphido complex [Ru2(CO)6(µ-PPh2)2]2 under a pressure of CO and the conversion of 2 into the ethyldiphenylphosphine complex [Ru2(CO)4(µ-O2CEt)2(PPh2Et)2]3 in the presence of ethylene and water have been studied; high-yield syntheses for the known complex 2 are also reported.

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Article information

DOI
https://doi.org/10.1039/DT9920002133
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 2133-2134

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Interplay of phosphido and phosphine ligands in dinuclear ruthenium complexes: implication in the catalytic hydroformylation of ethylene

A. Béguin, H. Böttcher, G. Süss-Fink and B. Walther, J. Chem. Soc., Dalton Trans., 1992, 2133 DOI: 10.1039/DT9920002133

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