X-Ray crystallographic studies of α-cyclodextrin (α-CD)–2- and –4-fluorophenol complexes indicate that the fluorine atom determines the guest orientations inside the α-CD cavity in both complexes, and accordingly that the hydroxy groups of 4-FC6H4OH and 2-FC6H4OH are located inside and outside the cavity, respectively.
M. Shibakami and A. Sekiya, J. Chem. Soc., Chem. Commun., 1992, 1742 DOI: 10.1039/C39920001742
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