The newly synthesized 6-derivative of β-cyclodextrin with histamine, bound through the N-1 of imidazole was used as a ligand for copper(II) ion, the ligand being characterized by NMR spectroscopy and the copper(II) complex by EPR spectroscopy; the complex was used in chiral ligand exchange chromatography and was able to separate L- and D-tryptophan.
V. Cucinotta, F. D'Alessandro, G. Impellizzeri and G. Vecchio, J. Chem. Soc., Chem. Commun., 1992, 1743 DOI: 10.1039/C39920001743
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