Allyl vinyl selenides easily undergo a [3.3] sigmatropic rearrangement under mild conditions to give γ-unsaturated reactive selenocarbonyl compounds, which can be trapped by cyclopentadiene or water.
Y. Vallée and M. Worrell, J. Chem. Soc., Chem. Commun., 1992, 1680 DOI: 10.1039/C39920001680
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