Xenon difluoride sequentially fluorinates Ir4(CO)12 dissolved in anhydrous HF yielding initially the novel neutral complexes mer- and fac-Ir(CO)3F3, which are characterised by 19F, 13C and 13C{19F} NMR spectroscopies, and finally [XeF][IrF6].
S. A. Brewer, J. H. Holloway, E. G. Hope and P. G. Watson, J. Chem. Soc., Chem. Commun., 1992, 1577 DOI: 10.1039/C39920001577
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