Issue 21, 1992

Electrophile induced reactions of medium ring vinyl- and 1,2-epoxy-silanes and related compounds

Abstract

Deuterium labelling studies confirm extensive trans-annular participation in acidolysis, acetylation and brominolysis of 1,2-epoxy-1-trimethylsilylcyclooctane and (E)-1-trimethylsilylcyclooctene, and require revision of previous mechanistic proposals.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1575-1577

Electrophile induced reactions of medium ring vinyl- and 1,2-epoxy-silanes and related compounds

A. P. Wells, B. H. Riches and W. Kitching, J. Chem. Soc., Chem. Commun., 1992, 1575 DOI: 10.1039/C39920001575

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