The absolute stereochemistry of the 1,7-dioxaspiro[5.5]undecan-3- and -4-ols that consistently accompany racemic 1,7-dioxaspiro[5.5]undecane in the female olive-fly (Bactrocera oleae) and in male B. cacuminatus and B. distincta have been determined by enantioselective syntheses and chiral gas chromatographic examinations, and substantial variation occurs between the species.
M. T. Fletcher, M. F. Jacobs, W. Kitching, S. Krohn, R. A. I. Drew, G. E. Haniotakis and W. Francke, J. Chem. Soc., Chem. Commun., 1992, 1457 DOI: 10.1039/C39920001457
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