Issue 19, 1992

Kinetic and structural information on metal cluster rearrangement in solution from EXAFS spectra

Abstract

Pt LIII edge EXAFS spectra for the spiked triangular cluster [Ru3Pt(µ-H)(µ42-CCBut)(CO)9(dppe)][dppe = 1,2-bis(diphenylphosphino)ethane]1 measured during its rearrangement in solution into the butterfly cluster [Ru3Pt(µ42-C[double bond, length half m-dash]CHBut)(CO)9(dppe)]2 show substantial changes, which provide both structural data on the complexes in solution and kinetic information on the course of the reaction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1456-1457

Kinetic and structural information on metal cluster rearrangement in solution from EXAFS spectra

A. J. Dent, L. J. Farrugia, A. G. Orpen and S. E. Stratford, J. Chem. Soc., Chem. Commun., 1992, 1456 DOI: 10.1039/C39920001456

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