α-Glucosides are prepared by connecting phenylthio 3,4,6-tri-O-acetyl-α-D-glucopyranoside and an alcohol or a phenol with a dimethylsilylene bridge followed by iodonium ion catalysed intramolecular glycosidation.
M. Bols, J. Chem. Soc., Chem. Commun., 1992, 913 DOI: 10.1039/C39920000913
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