Issue 7, 1992

Novel transformation of β-keto sulfoxides to unsaturated β-keto sulfides

Abstract

Reaction of β-keto sulfoxides with trimethylsilyl trifluoromethanesulfonate in the presence of diisopropylethylamine afforded the corresponding (1E,3E)-1-phenylthio-2-(trimethylsilyloxy)-1,3-diene derivatives which underwent hydrolysis to furnish 1-phenylthio-alk-3-en-2-one derivatives in high yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 560-561

Novel transformation of β-keto sulfoxides to unsaturated β-keto sulfides

H. Kosugi, K. Hoshino and H. Uda, J. Chem. Soc., Chem. Commun., 1992, 560 DOI: 10.1039/C39920000560

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements