α,α-Difluoro functionalized esters can be readily prepared in good yields from the reaction of iododifluoroacetates with alkenes and zinc in the presence of catalytic amounts of nickel dichloride hexahydrate.
Z. Yang and D. J. Burton, J. Chem. Soc., Chem. Commun., 1992, 233 DOI: 10.1039/C39920000233
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