Two isomers of a benzene-coordinated pentaruthenium–carbido cluster, [Ru5C(CO)12(µ3 : η2 : η2:η2-C6H6)]1 and [Ru5C(CO)12(η6-C6H6)]2 have been synthesised from [Ru5C(CO)15]3 and structurally characterised by single crystal X-ray diffraction; 1 is irreversibly converted to 2 on mild thermolysis.
P. J. Bailey, D. Braga, P. J. Dyson, F. Grepioni, B. F. G. Johnson, J. Lewis and P. Sabatino, J. Chem. Soc., Chem. Commun., 1992, 177 DOI: 10.1039/C39920000177
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