Issue 2, 1992

The synthesis, molecular structure and interconversion of two novel benzene-coordinated pentaruthenium–carbido cluster isomers [Ru5C(CO)123 : η2 : η2 : η2-C6H6)] and [Ru5C(CO)126-C6H6)]

Abstract

Two isomers of a benzene-coordinated pentaruthenium–carbido cluster, [Ru5C(CO)123 : η2 : η22-C6H6)]1 and [Ru5C(CO)126-C6H6)]2 have been synthesised from [Ru5C(CO)15]3 and structurally characterised by single crystal X-ray diffraction; 1 is irreversibly converted to 2 on mild thermolysis.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 177-178

The synthesis, molecular structure and interconversion of two novel benzene-coordinated pentaruthenium–carbido cluster isomers [Ru5C(CO)123 : η2 : η2 : η2-C6H6)] and [Ru5C(CO)126-C6H6)]

P. J. Bailey, D. Braga, P. J. Dyson, F. Grepioni, B. F. G. Johnson, J. Lewis and P. Sabatino, J. Chem. Soc., Chem. Commun., 1992, 177 DOI: 10.1039/C39920000177

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements