Nitration of phenol by 4-methyl-4-nitro-2,3,5,6-tetrabromocyclohexa-2,5-dienone in diethyl ether is a radical process involving reaction between the phenoxyl radical and NO2˙ that has escaped from a radical pair in which it was formed by homolytic fission of the C–N bond.
R. G. Coombes and J. H. Ridd, J. Chem. Soc., Chem. Commun., 1992, 174 DOI: 10.1039/C39920000174
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