Issue 24, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Porphyrinatoiron-catalysed reduction of styrene with sodium borohydride: proposed σ-alkyliron(III) complex as an intermediate

Koji Kano,   Masayuki Takeuchi,   Shizunobu Hashimoto  and  Zen-ichi Yoshida  

Abstract

5,10,15,20-Tetrakis(para-substituted phenyl)porphyrinatoiron(III) chloride complexes catalyse the reduction of styrene with NaBH4 to ethylbenzene and 2,3-diphenylbutane and the precursor is assumed to be the σ-alkyl complex (Xtpp)FeIII–PhCHMe.

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Article information

DOI
https://doi.org/10.1039/C39910001728
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1728-1729

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Porphyrinatoiron-catalysed reduction of styrene with sodium borohydride: proposed σ-alkyliron(III) complex as an intermediate

K. Kano, M. Takeuchi, S. Hashimoto and Z. Yoshida, J. Chem. Soc., Chem. Commun., 1991, 1728 DOI: 10.1039/C39910001728

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