The preparation of ruthenium ‘picket-fence’ porphyrins bearing optically active α-methoxy-α-(trifluoromethyl)phenylacetyl residues on both sides of the porphyrin plane is described; chiral recognition in the complexation of racemic benzylmethylphenylphosphine to the α,β,α,β isomer leads to the formation of one of three possible product diastereoisomers with high stereoselectivity (>95%).
P. Le Maux, H. Bahri and G. Simonneaux, J. Chem. Soc., Chem. Commun., 1991, 1350 DOI: 10.1039/C39910001350
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...