Stereocontrolled multiple functionalization of cycloheptadienoneiron complexes via enolate alkylation
Abstract
Alkylation of enolates from tricarbonyl(6-oxocycloheptadiene)iron occurs with complete stereoselectivity trans to the metal, while reduction of the ketone occurs with stereochemistry dictated by the boat conformation adopted by these molecules.
Please wait while we load your content...