Bis(pentamethylphenyl)methane shows exceptional reactivity in electron transfer owing to the formation of a novel π-stabilized cation radical, which is mechanistically delineated by time-resolved spectroscopy.
S. Sankararaman, W. Lau and J. K. Kochi, J. Chem. Soc., Chem. Commun., 1991, 396 DOI: 10.1039/C39910000396
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