Conformational energy calculations and geometrical arguments indicate that L-pyroglutamic acid (Glp) is an unusual amino acid residue in that its backbone conformational requirements are similar to those normally associated with a standard D-amino acid residue.
P. K. C. Paul, D. J. Osguthorpe and M. M. Campbell, J. Chem. Soc., Perkin Trans. 1, 1990, 3363 DOI: 10.1039/P19900003363
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