Issue 12, 1990

Intramolecular [2π+ 2π] photocycloaddition of Group 14 organometallic compounds bearing a styrene chromophore: a route to sila- and germa-cyclophanes and spiro compounds

Abstract

Irradiation of bis- and tetrakis-(4-vinylbenzyl)silanes and their germane analogue caused efficient intramolecular [2π+ 2π] cycloaddition, to give [2.3]sila- and germa-cyclophanes and also sila- and germa-spiro compounds.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1990, 3362-3363

Intramolecular [2π+ 2π] photocycloaddition of Group 14 organometallic compounds bearing a styrene chromophore: a route to sila- and germa-cyclophanes and spiro compounds

K. Nakanishi, K. Mizuno and Y. Otsuji, J. Chem. Soc., Perkin Trans. 1, 1990, 3362 DOI: 10.1039/P19900003362

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