Conjugate addition of N-benzyl-N′,N′-dimethylethylenediamine to acrylamide affords a chelating amide in which the amide carbonyl can coordinate to the bound metal only via a six-membered chelate; this compound demonstrates copper(II)-catalysed amide hydrolysis, in which each metal acts on at least five equivalents of substrate.
B. F. Duerr and A. W. Czarnik, J. Chem. Soc., Chem. Commun., 1990, 1707 DOI: 10.1039/C39900001707
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