In the solid-state a monomethine cyanine TCNQ˙– salt and an 18-crown-6 K+ TCNQ˙– complex both contain isolated, vertically stacked, TCNQ dimers which, despite the fundamentally different nature and location of the two cations, both show evidence for thermally excited triplet excitons.
M. C. Grossel, F. A. Evans, J. A. Hriljac, K. Prout and S. C. Weston, J. Chem. Soc., Chem. Commun., 1990, 1494 DOI: 10.1039/C39900001494
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