Thermolysis of N-t-butyl- and N-cumyl-2,2-dichlorocyclopropylimines gives selectively 3-chloropyrroles in polar solvents and 2-chloro derivatives with added base.
S. Kagabu and I. Kawai, J. Chem. Soc., Chem. Commun., 1990, 1393 DOI: 10.1039/C39900001393
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