An asymmetric total synthesis of the naphthylisoquinoline alkaloid (–)-O-methylancistrocladine (2) is described; the synthetic method also provides routes to the atropisomer O-methylhamatine (4) and the enantiomers of these alkaloids.
M. A. Rizzacasa and M. V. Sargent, J. Chem. Soc., Chem. Commun., 1990, 894 DOI: 10.1039/C39900000894
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