SCHEDULED MAINTENANCE
The compound [8,8-(PPh3)2-8,7-RhSB9H10], (1), has a formal closo electron count but a nido structure, exhibits unusual fluxional behaviour in solution and reacts to give both closo and nido compounds, e.g., closo-[2,3-(PPh3)2-3-(Cl)-µ-2; 3-(Cl)-2-(Ph2P[graphic omitted]H8], (2), and nido-[8,8-(PPh3)2-µ-8;9-(S2CH)-8,7-RhSB9H9], (3); the structures of (1), (2), and (3) were determined by X-ray crystallographic methods.
G. Ferguson, M. C. Jennings, A. J. Lough, S. Coughlan, T. R. Spalding, J. D. Kennedy, X. L. R. Fontaine and B. Štibr, J. Chem. Soc., Chem. Commun., 1990, 891 DOI: 10.1039/C39900000891
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