Issue 1, 1990

A new trifluorosilyl exchange reagent: reactions of Cd(SiF3)2·glyme (glyme = dimethoxyethane) with dibromo metal phosphine complexes of platinum, palladium, and nickel yield trifluorosilyl substituted dialkyl compounds

Abstract

The reaction of excess Cd(SiF3)2·glyme (glyme = dimethoxyethane) with trimethylphosphine metal dibromides of platinum, palladium, and nickel yielded the trifluorosilyl substituted dialkyl compounds trans-Pt(SiF3)2(PMe3)2, Pd(SiF3)2(PMe3)2, and Ni(SiF3)2(PMe3)3.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 65-66

A new trifluorosilyl exchange reagent: reactions of Cd(SiF3)2·glyme (glyme = dimethoxyethane) with dibromo metal phosphine complexes of platinum, palladium, and nickel yield trifluorosilyl substituted dialkyl compounds

M. A. Guerra and R. J. Lagow, J. Chem. Soc., Chem. Commun., 1990, 65 DOI: 10.1039/C39900000065

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