A new porphyrinatoiron complex, 5,10,15,20-tetrakis(2,6-bispivaloyloxyphenyl)porphyrinatoriron(II), has been synthesized; axial-base ligation was sterically depressed by the four ester groups on each side of the porphyrin plane and a stable dioxygen adduct formed reversibly at 25 °C in toluene.
T. Komatsu, E. Hasegawa, H. Nishide and E. Tsuchida, J. Chem. Soc., Chem. Commun., 1990, 66 DOI: 10.1039/C39900000066
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