SCHEDULED MAINTENANCE
2,2′:6′,2″:6″2‴:6‴,2â�—-Quinquepyridine (qpy) forms a binuclear complex [(tpy)Ru(qpy)Ru(tpy)Cl][PF6]3(tpy = 2,2′:6′,2″-terpyridine) which has been structurally characterised and shown t o possess a helical structure with two six-co-ordinate ruthenium centres bridged by the qpy ligand; the complex is electrochemically active, but there are no significant interactions between the two metal centres.
C. J. Cathey, E. C. Constable, M. J. Hannon, D. A. Tohcer and M. D. Ward, J. Chem. Soc., Chem. Commun., 1990, 621 DOI: 10.1039/C39900000621
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