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Issue 8, 1990
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A single stranded diruthenium(II) helical complex

Abstract

2,2′:6′,2″:6″2‴:6‴,2â�—-Quinquepyridine (qpy) forms a binuclear complex [(tpy)Ru(qpy)Ru(tpy)Cl][PF6]3(tpy = 2,2′:6′,2″-terpyridine) which has been structurally characterised and shown t o possess a helical structure with two six-co-ordinate ruthenium centres bridged by the qpy ligand; the complex is electrochemically active, but there are no significant interactions between the two metal centres.

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Article type: Paper
DOI: 10.1039/C39900000621
J. Chem. Soc., Chem. Commun., 1990, 621-622

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    A single stranded diruthenium(II) helical complex

    C. J. Cathey, E. C. Constable, M. J. Hannon, D. A. Tohcer and M. D. Ward, J. Chem. Soc., Chem. Commun., 1990, 621
    DOI: 10.1039/C39900000621

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