Searches for the exo and endo transition states for the ene reaction of methyl acrylate with propene, using split-valence 3-21G and 6-31G basis sets, suggest less asynchronous character in the bond reorganization as compared with the parent ene reaction between propene and ethylene.
T. Uchimaru, S. Tsuzuki, K. Tanabe and Y. Hayashi, J. Chem. Soc., Chem. Commun., 1989, 1861 DOI: 10.1039/C39890001861
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