Issue 23, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

Facile conversion of a cationic MoIV phosphinimato complex into an anionic nitrido-bridged dimer with a bis(trimethylphosphine)iminium counterion

Vernon C. Gibson,   David N. Williams  and  William Clegg  

Abstract

[Mo(NPMe3)Cl2(PMe3)3]Cl is formed in 82% yield upon treatment of [Mo(N)Cl3] with four equivalents of trimethylphosphine in CH2Cl2 and rearranges to the nitrido-bridged dimer [(Me3P)2Cl3MoNMoCl3(PMe3)2][Me3PNPMe3] upon standing at room temperature in CH2Cl2; X-ray structural analyses of these compounds are reported.

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Article information

DOI
https://doi.org/10.1039/C39890001863
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1863-1864

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Facile conversion of a cationic MoIV phosphinimato complex into an anionic nitrido-bridged dimer with a bis(trimethylphosphine)iminium counterion

V. C. Gibson, D. N. Williams and W. Clegg, J. Chem. Soc., Chem. Commun., 1989, 1863 DOI: 10.1039/C39890001863

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